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Year 2024
 
Vol 65, Issue 5, [10 - 2024]

A batch experiment for determining retardation factors of Ni2+, Zn2+, Cd2+, and Pb2+ in unsaturated zone of unconsolidated formation in Man Xa and Chau Khe communes, Bac Ninh province

DOI:10.46326/JMES.2024.65(5).10

  • Affiliations:

    1 Vietnam Association of Hydrogeology, Hanoi, Vietnam
    2 Institute for Nuclear Science and Technology, Hanoi, Vietnam
    3 Hanoi University of Mining and Geology, Hanoi, Vietnam

  • *Corresponding:
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  • Received: 28th-Feb-2024
  • Revised: 3rd-July-2024
  • Accepted: 20th-Aug-2024
  • Online: 1st-Oct-2024
Pages: 97 - 108
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Abstract:

This paper presents the results of a batch equilibrium adsorption experiment aimed at determining the retardation factors (R) of four heavy metal ions Ni2+, Zn2+, Cd2+, and Pb2+due to their adsorption on soil particles in an unsaturated zone. The experiments were carried out using clay-loam soil samples collected from Man Xa commune, Yen Phong district and Chau Khe commune, Tu Son city, Bac Ninh province, at two depths of 0÷15 cm and 15÷30 cm from the ground surface. The experimental adsorption procedure is followed by the equilibrium adsorption method. Results obtained showed that the adsorption of the 4 ions on soil particles in the two study areas is linear and followed the Freundlich model. This allows one to estimate the retardation factors of the 4 ions based on a model that includes the equilibrium adsorption coefficient (Kd), soil bulk density ((B) and soil porosity ((). The R values of the four ions in the soils of Man Xa and Chau Khe vary from 2.30÷16.27 depending on the nature of the adsorbate. Ion Pb2+ possesses the highest R value for Man Xa soil. The adsorption of Pb2+ is suggested to be followed by both physical and chemo-adsorption mechanisms, it participated in an ion-exchange process with protonium ion of goethite present in the soil, making the R value of the species to be different.

How to Cite
Dang, N.Duc, Vu, H.Thi, Mai, K.Dinh, Nguyen, K.Van, Nguyen, L.Van, Tran, L.Vu, Duong, T.Thanh Thi, Dao, B.Duc and Kieu, A.Van Thi 2024. A batch experiment for determining retardation factors of Ni2+, Zn2+, Cd2+, and Pb2+ in unsaturated zone of unconsolidated formation in Man Xa and Chau Khe communes, Bac Ninh province (in Vietnamese). Journal of Mining and Earth Sciences. 65, 5 (Oct, 2024), 97-108. DOI:https://doi.org/10.46326/JMES.2024.65(5).10.
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