Archives
 
Year 2021
 
Vol 62, Issue 3, [06 - 2021] - Full papers

Highly photocatalytic activity of natural halloysite - based material for the treatment of dyes in wastewater

DOI:10.46326/JMES.2021.62(3).03

  • Affiliations:

    Hanoi University of Mining and Geology, Hanoi, Vietnam

  • *Corresponding:
    This email address is being protected from spambots. You need JavaScript enabled to view it.
  • Received: 19th-Dec-2020
  • Revised: 17th-Apr-2021
  • Accepted: 15th-May-2021
  • Online: 30th-June-2021
Pages: 19 - 28
Views: 2596
View onlineView online
Downloads: 1107
Downdload PDF
★★★★★Rating: 1.0, Total rating: 110
  • ★
  • ★
  • ★
  • ★
  • ★
Yours rating

Abstract:

In this study, the halloysite nanotube material will be fabricated from a natural halloysite mineral and used as a support for the photocatalytic activity phase based on TiO2. The material is characterized by modern physicochemical methods such as XRD, SEM, BET, UV - vis spectrum, and EDX. Accordingly, the refined halloysite has a nanoscale with a length of about 1.3 μm and a capillary size of about 5 nm. After the deposition of Ag - TiO2 on the halloysite, the specific surface of the material measured by the BET method was about 60 m2/g, and the structure of the halloysite was intact. The band - gap energy of as - prepared materials is also significantly improved in comparison to pure TiO2, makes the material capable of absorbing longer wavelengths of light in the photocatalytic process. The Photocatalyst based on Halloysite and TiO2 showed very high efficiency, up to more than 95% in the decomposition of typical organic pollutant RR - 195. This result shows great potential in this novel material in environmental treatment applications.

How to Cite
Ngo, S.Ha, Pham, N.Xuan and Tran, T.Ngoc 2021. Highly photocatalytic activity of natural halloysite - based material for the treatment of dyes in wastewater. Journal of Mining and Earth Sciences. 62, 3 (Jun, 2021), 19-28. DOI:https://doi.org/10.46326/JMES.2021.62(3).03.
References

Ansari, S. A., Khan, M. M., Ansari, M. O., Lee, J. and Cho, M. H., (2013). Biogenic synthesis, photocatalytic, and photoelectrochemical performance of Ag - ZnO nanocomposite. J. Phys. Chem. C 117, 27023 - 27030.

B. Szczepanik, P. Rogala, P.M. Słomkiewicz, D. Banaś, A. Kubala - Kukuś, I. Stabrawa, (2017). Synthesis, characterization and photocatalytic activity of TiO2 - halloysite and Fe2O3 - halloysite nanocomposites for photodegradation of chloroanilines in water, Appl. Clay Sci. 149, 118 - 126.

G. Guo, B. Yu, P. Yu, X. Chen, (2009). Synthesis and photocatalytic applications of Ag/TiO2 - nanotubes. Talanta. 79, 570 - 575.

Grabowska, E., Zaleska, A., Sorgues, S., Kunst, M., Etcheberry, A., Colbeau - Justin, C., Remita, H., (2013). Modification of titanium (IV) dioxide with small silver nanoparticles: application in photocatalysis. J. Phys. Chem. C 117, 1955 - 1962.

H. Dong, Zeng, Tang, . Fan, Zhang, He, He, (2015). An overview on limitations of TiO2 - based particles for photocatalytic degradation of organic pollutants and the corresponding countermeasures, Water Res. 79, 128 - 146.

K. Imamura, E. Ikeda, T. Nagayasu, T. Sakiyama, K. Nakanishi, (2002). Adsorption behavior of methylene blue and its congeners on a stainless steel surface. J. Colloid Interface Sci. 245, 50 - 57.

Khan, M. M., Ansari, S. A., Amal, M. I., Lee, J. and Cho, M. H., (2013). Highly visible light active Ag/TiO2 nanocomposites synthesized using an electrochemically active biofilm: a novel biogenic approach. Nanoscale 5, 4427 - 4435.

N. Cotolan, M. Rak, M. Bele, A. Cör, L.M. Muresan, I. Milošev, (2016). Sol - gel synthesis, characterization and properties of TiO2 and Ag - TiO2 coatings on titanium substrate. Surf. Coatings Technol. A 307, 790 - 799.

Ohtani, B., Iwai, K., Nishimoto, S. and Sato, S., (1997). Role of platinum deposits on titanium (IV) oxide particles: structural and kinetic analyses of photocatalytic reaction in aqueous alcohol and amino acid solutions. J. Phys. Chem. B 101, 3349 - 3359.

Oros - Ruiz, S., Zanella, R., López, R., Hernández - Gordillo, A. and Gómez, R., (2013). Photocatalytic hydrogen production by water/methanol decomposition using Au/TiO2 prepared by deposition - precipitation with urea. J. Hazard. Mater. 263, 2 - 10.

R. Kamble, M. Ghag, S. Gaikawad, B. Panda, 2012. Halloysite Nanotubes and Applications: A Review. J. Adv. Sci. Res. 3, 25 - 29.

S. Bagane, M., Guiza, (2000). Removal of a dye from textile effluents by adsorption.Ann. Chim. Sci. Mater 25, 615 - 626.

S. M., K. Natarajan, (2015). Antibiofilm Activity of Epoxy/Ag - TiO2 Polymer Nanocomposite Coatings against Staphylococcus Aureus and Escherichia Coli. Coatings. 5 (2), 95 - 114.

S. Rooj, A. Das, V. Thakur, R.N. Mahaling, A.K. Bhowmick, G. Heinrich, (2010). Preparation and properties of natural nanocomposites based on natural rubber and naturally occurring halloysite nanotubes. Mater. Des. 31, 2151 - 2156

S. A. Amin, M. Pazouki, A. Hosseinnia, (2009). Synthesis of TiO2 - Ag nanocomposite with sol - gel method and investigation of its antibacterial activity against E. coli. Powder Technol. 196, 241 - 245.

Shan, Z., Wu, J., Xu, F., Huang, F. - Q. and Ding, H., (2008). Highly effective silver/semiconductor photocatalytic composites prepared by a silver mirror reaction. J. Phys. Chem. C 112, 15423 - 15428.

W.I. Abdel Fattah, M.M. Gobara, W. El - Hotaby, S.F.M. Mostafa, G.W. Ali, (2016). Coating stainless steel plates with Ag/TiO2 for chlorpyrifos decontamination.Mater. Res. Express. 3 (5).

Y. Zhang, A. Tang, H. Yang, J. Ouyang, (2016). Applications and interfaces of halloysite nanocomposites. Appl. Clay Sci. 119, 8 - 17.

Zhou, X., Liu, G., Yu, J. and Fan, W. Surface plasmon resonance - mediated photocatalysis by noble metal - based composites under visible light. J. Mater. Chem. 22, 21337 - 21354 (2012).

Zielińska, A., Kowalska, E., Sobczak, J. W., Łącka, I.,Gazda, M., Ohtani, B., Hupka, J., Zaleska, A., (2010), Silver - doped TiO2 prepared by microemulsion method: surface properties, bio - and photoactivity. Sep. Purif. Technol. 72, 309 - 318.

Other articles